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Electrochemiluminescence Sensor for Selective Preconcentration and Sensitive Detection of Napropamide Using Water‐Soluble Sulfonated Graphene 下载免费PDF全文
A novel electrochemiluminescence (ECL) sensor for napropamide determination was prepared using the water‐soluble sulfonated graphene (sulfonated‐G) as solid‐phase microextraction (SPME) material, based on selective preconcentration of target onto an electrode and followed by luminol ECL detection. The effects of pH, adsorption time, buffer solution and the luminescence agent on ECL intensity were optimized. Under the optimized conditions (pH 6; adsorption time 5 min; buffer solution pH 11.0 Na2CO3 aHCO3; luminescence agent luminol; stirring speed 400 rpm), the lowest detection limits (1.0 µg L−1) and good linear range (r2≥0.99) were obtained for the analyte, indicating the superior performance of Nafion/sulfonated‐G/GCE for detecting napropamide. 相似文献
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A simple, cheap and non-enzymatic colorimetric strategy for glucose detection has been designed based on the interactions between a phenylboronic acid (PBA) derivative, which is coupled with gold nanoparticles (AuNPs) as the colorimetric reporters, and glucose. The PBA-AuNPs hybrid system proposed here exhibits ordered photochemistry behaviors upon the addition of glucose at different pH values. There are two linear regions of glucose concentration for the glucose sensor at different pH values, i.e., between 0.1 mmol/L and 9.8 mmol/L at pH 6 with the detection limit of 64μmol/L and between 0 and 6.5 mmol/L with the detection limit of 48 μmol/L at pH 9, respectively. To test the practicality of the sensor system, we also applied this assay to detect a glucose sample in the artificial saliva. 相似文献
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电感耦合等离子体原子发射光谱法测定人造金刚石中铁、钴、锰、镍 总被引:1,自引:0,他引:1
1引言近年来,我国人造金刚石的产量和应用有了很大的发展。以现有的人造金刚石合成技术,通常以Fe,Ni,Co,Mn等元素组成的合金作为触媒,这使人造金刚石中极易残留这些金属组成的包裹体。诸多研究表明,包裹体含量和分布情况对人造金刚石的性能有着重要影响[1]。经查阅文献,已有使用X射线荧光光谱法对人造金刚石中杂质元素含量进行半定量分析的报道[2]。电感耦合等离子体发射光谱法(ICP-AES)被广泛应用于岩矿、土壤样品中多元素分析[3]。本实验以在大气气氛中高温灰化和混合酸对样品进行前处理,采用ICP-AES测定人造金刚石中Fe,Co,Ni和Mn。本方法操作简便,处理效果良好。 相似文献
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Qingyun Zheng Tian Wang Guo-Chao Chu Chong Zuo Rui Zhao Xin Sui Linzhi Ye Yuanyuan Yu Jingnan Chen Xiangwei Wu Wenhao Zhang Prof. Haiteng Deng Prof. Jing Shi Dr. Man Pan Prof. Yi-Ming Li Prof. Lei Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(32):13598-13603
Triazole-based deubiquitylase (DUB)-resistant ubiquitin (Ub) probes have recently emerged as effective tools for the discovery of Ub chain-specific interactors in proteomic studies, but their structural diversity is limited. A new family of DUB-resistant Ub probes is reported based on isopeptide-N-ethylated dimeric or polymeric Ub chains, which can be efficiently prepared by a one-pot, ubiquitin-activating enzyme (E1)-catalyzed condensation reaction of recombinant Ub precursors to give various homotypic and even branched Ub probes at multi-milligram scale. Proteomic studies using label-free quantitative (LFQ) MS indicated that the isopeptide-N-ethylated Ub probes may complement the triazole-based probes in the study of Ub interactome. Our study highlights the utility of modern protein synthetic chemistry to develop structurally and new families of tool molecules needed for proteomic studies. 相似文献
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Single crystal of lithium terbium tungstate LiTb(WO4)2 has been grown by the flux method. The crystal structure was refined from single-crystal X-ray data. It crystallizes in tetragonal system, space group I41/a with a = 5.1749(9), c = 11.1953(19) ?, V = 299.81(12) ?~3, Z = 2, Mr = 661.56, Dc = 7.328 g/cm^3, F(000) = 560, μ(MoKα) = 49.94 mm-1, R(F^2 > 2σ(F^2)) = 0.026 and wR(F^2) = 0.070. It features a typical scheelite-type structure composed of two-direction packing of isolated WO4 tetrahedra. Li and Tb atoms in the structure occupy the same crystallographic site. Moreover, a series of solid solution phosphors LiTb(1-x)Eux(WO4)2(x = 0.004~0.1) were synthesized by high temperature solid-state reactions. The phosphors could be effectively excited by a wavelength range from 379 to 487 nm, which matches well with the UV and near-UV LED chip. The emission color of the phosphor can be tuned from green, through yellow to red by simply adjusting the relative Eu3+ and Tb3+ concentration due to the Tb3+ to Eu3+ energy transfer. 相似文献
88.
Dong Yang Pei Liu Wanran Lin Shanglin Sui Long‐Biao Huang Ben Bin Xu Jie Kong 《化学:亚洲杂志》2020,15(16):2499-2504
Hyperbranched polymers have garnered much attention due to attractive properties and wide applications, such as drug‐controlled release, stimuli‐responsive nano‐objects, photosensitive materials and catalysts. Herein, two types of novel hyperbranched poly(ester‐enamine) (hb‐PEEa) were designed and synthesized via the spontaneous amino‐yne click reaction of A2 monomer (1, 3‐bis(4‐piperidyl)‐propane (A2a) or piperazine (A2b)) and B3 monomer (trimethylolpropanetripropiolate). According to Flory's hypothesis, gelation is an intrinsic problem in an ideal A2+B3 polymerization system. By controlling the polymerization conditions, such as monomer concentration, molar ratio and rate of addition, a non‐ideal A2+B3 polymerization system can be established to avoid gelation and to synthesize soluble hb‐PEEa. Due to abundant unreacted alkynyl groups in periphery, the hb‐PEEa can be further functionalized by different amino compounds or their derivates. The as‐prepared amphiphilic PEG‐hb‐PEEa copolymer can readily self‐assemble into micelles in water, which can be used as surfactant to stabilize Au nanoparticles (AuNPs) during reduction of NaBH4 in aqueous solution. As a demonstration, the as‐prepared PEG‐hb‐PEEa‐supported AuNPs demonstrate good dispersion in water, solvent stability and remarkable catalytic activity for reduction of nitrobenzene compounds. 相似文献
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